Remarkably stable chelating bis-N-heterocyclic carbene adducts of phosphorus(i) cations.
نویسندگان
چکیده
A convenient one-pot synthesis of chelating bis-N-heterocyclic carbene-ligated P(I) salts is described. The solid state structures of these remarkably stable phosphamethine cyanine dyes with various N-alkyl groups and counter-anions are reported, and initial reactivity results are discussed.
منابع مشابه
The synthesis, characterisation and electronic structure of N-heterocyclic carbene adducts of P(I) cations.
Two different syntheses of N-heterocyclic carbene complexes of P(I) cations are presented; the structural features of these phosphamethine cyanine salts, in conjunction with the results of computational investigations, provide insight into the nature of the bonding of these heavy allene analogues.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 36 شماره
صفحات -
تاریخ انتشار 2015